Oreimo is the closest to such a ऐनीमे since Kirino may या may not be one of the और famous tsundere around. (Keep in mind that even if a boy there is the main character its और focused around her.)
Hentai ouji to waranai neko ( In english "The hentai prince and the stray cat" ) also features a tsundere character named Azuki Azusa, altough she doesnt get as much attention as Kirino get (Also a guy here is the main protag. )