Yes, they broke up in Frost & Fire. Finn tried to get back to Princess Bubblegum in the following episode, Too Old, but he rejected him because she was focusing on some नींबू child (I forgot his name). At the end of Too Old, Finn कहा he would try to fix things up with Flame. In Earth & Water, FP becomes Flame Queen. When Finn asked if they were still going out, she कहा no but they could still be good फ्रेंड्स if he was completely honest to her.
Not really, in that episode FP कहा she needed some time alone but in the following episodes she कहा they can still be फ्रेंड्स and she took over as her her father